BCS pairing and superconductivity
Build a paired fermionic variational state, calculate its gapped excitations, and identify the limits of weak-coupling mean field.
On this page
The question for today
What you’ll understand
- Explain why a Fermi surface makes weak attraction significant.
- Calculate a Bogoliubov quasiparticle energy and coherence factors.
- Separate pair formation, phase stiffness, and electromagnetic response.
Fermions cannot all occupy one single-particle state, yet an interacting Fermi system can develop coherent pairing between opposite momenta. BCS theory describes that reorganization with a variational state mixing empty and doubly occupied momentum pairs. The result is much more than two electrons orbiting together: many overlapping pairs collectively alter the excitation spectrum. We will work with a clean, uniform, weak-coupling, spin-singlet s-wave model and keep its assumptions visible throughout the calculation.
The Fermi surface changes the pairing problem
Assume an effective attractive interaction within an energy window around the Fermi surface. In conventional superconductors this attraction can emerge from electron-phonon dynamics after other degrees of freedom are treated appropriately; it is not the assertion that bare Coulomb repulsion becomes attractive at every distance. The idealized reduced model takes a constant pairing matrix element in that window and uses the normal-state density of states as approximately constant. Weak coupling means its dimensionless product with the attraction is small.
The Cooper problem shows that the available states near an otherwise filled Fermi sea make arbitrarily weak attraction unstable to pairing in the idealized channel. BCS goes beyond one added pair by varying coherent amplitudes for all paired momenta. A factor mixes an empty pair sector with an occupied one. Normalize each factor so . This state does not have a fixed particle number, although number projection is possible and bulk number-conserving observables can be treated consistently.
A gap reshapes the elementary excitations
Define as normal-state single-particle energy measured from the chemical potential. Decoupling the interaction in the pair channel produces a quadratic Hamiltonian for particle and hole amplitudes. Its positive excitation energy is . The transformation preserves fermionic anticommutation relations. Although both Bose and Fermi calculations use the name Bogoliubov, their algebra and normalization differ; the identical name is not permission to reuse a bosonic formula.
The gap is determined self-consistently rather than inserted as a free extra interaction. At zero temperature in the weak-coupling constant-density-of-states model, its scale is exponentially small compared with the cutoff window. This exponential dependence explains why modest interaction changes can greatly change a predicted transition scale. A fully gapped isotropic s-wave state has minimum excitation energy ; creating two quasiparticles typically requires at least . Other pairing symmetries can have nodes, so a universal hard gap should not be inferred for every superconductor.
Pairing and coherent superconducting response
A gap or a two-body bound state alone does not prove a material carries a robust supercurrent. Phase stiffness describes the energy cost of spatially twisting the collective phase. Coupling that phase consistently to electromagnetism produces screening and the Meissner response. The pair charge has magnitude twice the electron charge. Calling this simply a broken local gauge symmetry is misleading: gauge transformations are redundancies, and observable statements concern correlations and electromagnetic response.
The usual finite-temperature BCS transition is a mean-field result, most reliable away from the narrow fluctuation region in suitable three-dimensional weak-coupling systems. In strictly two-dimensional neutral systems, or suitable thin-film limits, phase fluctuations and vortex physics can control the transition instead of the mean-field pair-formation temperature. Strong coupling, disorder, multiband structure, and unconventional pairing require extensions. Compare the assumptions with an experiment before interpreting a fitted gap as evidence for one unique pairing mechanism.
Work it through
Particle and hole weights near a gap
Take a real uniform gap Δ = 2 meV and a mode with ξ = 3 meV in the zero-temperature mean-field model. Calculate its excitation energy and pair occupation weight.
Compute .
Then , and . These weights sum to one.
At , the same formulas give and . The Fermi-surface mode has equal particle-hole weights, not zero excitation energy.
Pairing smooths occupation across the normal-state Fermi surface and opens a 2 meV single-quasiparticle gap in this specified s-wave model.
The living notebook
Explore the model
Interactive lab · quantum
Inspect one normalized pair-sector analogy
The lab displays a single pure two-level state cos(θ/2)|0⟩+exp(iφ)sin(θ/2)|1⟩. Interpret its two basis states only as an analogy for the empty and occupied sector of one momentum pair. Changing θ exposes normalized weights, while φ changes relative phase. It does not solve a gap equation or model a macroscopic superconductor.
- Probability |0⟩
- 71.1%
- Probability |1⟩
- 28.9%
- Bloch (x, y, z)
- 0.78, 0.45, 0.42
A normalized two-level pure state, not an interacting field simulation. Playback adds one radian per second to the relative phase; basis probabilities stay fixed. Parameter changes pause playback and recompute the model at the current elapsed time. Reset restores both parameters and returns time to zero. Playback starts paused. Adjust either parameter, then choose Play or Step.
Look forA normalized two-amplitude factor is inspectable. Collective pairing, temperature, stiffness, and electromagnetic screening require the many-body calculation beyond this lab.
Pause & reason
Check your understanding
Your turn
Try it yourself
Reverse the sign of ξ in the worked example while keeping Δ fixed. Find E and |v|², and explain the physical difference.
Take a moment to make a prediction or work it out on paper. Open a hint when you need one.
Give me a hint
The spectrum contains ξ², but the coherence factor contains ξ itself.
Compare with the solution
For ξ = −3 meV, E remains √13 meV ≈ 3.6056 meV. The occupation weight becomes (1+3/√13)/2 ≈ 0.9160. Modes below and above the chemical potential can have the same excitation energy while differing in their particle-hole character and ground-state occupation.
Keep the idea
Take it with you
- BCS pairing reorganizes many states near a Fermi surface.
- The gap and coherence factors arise from a self-consistent paired mean field.
- Phase stiffness and electromagnetic response add information beyond a pairing gap.
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