research30 min studyLesson 68 in Physics

BCS pairing and superconductivity

Build a paired fermionic variational state, calculate its gapped excitations, and identify the limits of weak-coupling mean field.

On this page

What you’ll understand

  • Explain why a Fermi surface makes weak attraction significant.
  • Calculate a Bogoliubov quasiparticle energy and coherence factors.
  • Separate pair formation, phase stiffness, and electromagnetic response.

Fermions cannot all occupy one single-particle state, yet an interacting Fermi system can develop coherent pairing between opposite momenta. BCS theory describes that reorganization with a variational state mixing empty and doubly occupied momentum pairs. The result is much more than two electrons orbiting together: many overlapping pairs collectively alter the excitation spectrum. We will work with a clean, uniform, weak-coupling, spin-singlet s-wave model and keep its assumptions visible throughout the calculation.

The Fermi surface changes the pairing problem

Assume an effective attractive interaction within an energy window Ω\Omega around the Fermi surface. In conventional superconductors this attraction can emerge from electron-phonon dynamics after other degrees of freedom are treated appropriately; it is not the assertion that bare Coulomb repulsion becomes attractive at every distance. The idealized reduced model takes a constant pairing matrix element in that window and uses the normal-state density of states as approximately constant. Weak coupling means its dimensionless product with the attraction is small.

The Cooper problem shows that the available states near an otherwise filled Fermi sea make arbitrarily weak attraction unstable to pairing in the idealized channel. BCS goes beyond one added pair by varying coherent amplitudes for all paired momenta. A factor uk+vkck↑†c−k↓†u_k+v_k c^\dagger_{k\uparrow}c^\dagger_{-k\downarrow} mixes an empty pair sector with an occupied one. Normalize each factor so ∣uk∣2+∣vk∣2=1|u_k|^2+|v_k|^2=1. This state does not have a fixed particle number, although number projection is possible and bulk number-conserving observables can be treated consistently.

∣BCS⟩=∏k(uk+vkck↑†c−k↓†)∣0⟩,∣uk∣2+∣vk∣2=1|\mathrm{BCS}\rangle=\prod_k\left(u_k+v_kc^\dagger_{k\uparrow}c^\dagger_{-k\downarrow}\right)|0\rangle,\qquad |u_k|^2+|v_k|^2=1
Each factor uses one up-spin k mode and one down-spin −k mode, so those single-particle modes are not counted twice. This is a paired variational ansatz, not an exact state for arbitrary interactions.↔ Scroll wide equations horizontally.

A gap reshapes the elementary excitations

Define ξk\xi_k as normal-state single-particle energy measured from the chemical potential. Decoupling the interaction in the pair channel produces a quadratic Hamiltonian for particle and hole amplitudes. Its positive excitation energy is Ek=ξk2+∣Δ∣2E_k=\sqrt{\xi_k^2+|\Delta|^2}. The transformation preserves fermionic anticommutation relations. Although both Bose and Fermi calculations use the name Bogoliubov, their algebra and normalization differ; the identical name is not permission to reuse a bosonic formula.

The gap is determined self-consistently rather than inserted as a free extra interaction. At zero temperature in the weak-coupling constant-density-of-states model, its scale is exponentially small compared with the cutoff window. This exponential dependence explains why modest interaction changes can greatly change a predicted transition scale. A fully gapped isotropic s-wave state has minimum excitation energy ∣Δ∣|\Delta|; creating two quasiparticles typically requires at least 2∣Δ∣2|\Delta|. Other pairing symmetries can have nodes, so a universal hard gap should not be inferred for every superconductor.

Ek=ξk2+∣Δ∣2,∣vk∣2=12(1−ξkEk),∣uk∣2=1−∣vk∣2E_k=\sqrt{\xi_k^2+|\Delta|^2},\qquad |v_k|^2=\frac12\left(1-\frac{\xi_k}{E_k}\right),\qquad |u_k|^2=1-|v_k|^2
These are zero-temperature coherence factors for a uniform singlet mean-field state. Δ and ξ have energy units, while u and v are dimensionless amplitudes.↔ Scroll wide equations horizontally.

Pairing and coherent superconducting response

A gap or a two-body bound state alone does not prove a material carries a robust supercurrent. Phase stiffness describes the energy cost of spatially twisting the collective phase. Coupling that phase consistently to electromagnetism produces screening and the Meissner response. The pair charge has magnitude twice the electron charge. Calling this simply a broken local gauge symmetry is misleading: gauge transformations are redundancies, and observable statements concern correlations and electromagnetic response.

The usual finite-temperature BCS transition is a mean-field result, most reliable away from the narrow fluctuation region in suitable three-dimensional weak-coupling systems. In strictly two-dimensional neutral systems, or suitable thin-film limits, phase fluctuations and vortex physics can control the transition instead of the mean-field pair-formation temperature. Strong coupling, disorder, multiband structure, and unconventional pairing require extensions. Compare the assumptions with an experiment before interpreting a fitted gap as evidence for one unique pairing mechanism.

Particle and hole weights near a gap

Take a real uniform gap Δ = 2 meV and a mode with ξ = 3 meV in the zero-temperature mean-field model. Calculate its excitation energy and pair occupation weight.

  1. Compute E=32+22 meV=13 meV≈3.6056 meVE=\sqrt{3^2+2^2}\,\mathrm{meV}=\sqrt{13}\,\mathrm{meV}\approx3.6056\,\mathrm{meV}.

  2. Then ∣v∣2=(1−3/13)/2≈0.0840|v|^2=(1-3/\sqrt{13})/2\approx0.0840, and ∣u∣2≈0.9160|u|^2\approx0.9160. These weights sum to one.

  3. At ξ=0\xi=0, the same formulas give E=2 meVE=2\,\mathrm{meV} and ∣u∣2=∣v∣2=1/2|u|^2=|v|^2=1/2. The Fermi-surface mode has equal particle-hole weights, not zero excitation energy.

The result

Pairing smooths occupation across the normal-state Fermi surface and opens a 2 meV single-quasiparticle gap in this specified s-wave model.

Explore the model

Interactive lab

Interactive lab · quantum

Inspect one normalized pair-sector analogy

The lab displays a single pure two-level state cos(θ/2)|0⟩+exp(iφ)sin(θ/2)|1⟩. Interpret its two basis states only as an analogy for the empty and occupied sector of one momentum pair. Changing θ exposes normalized weights, while φ changes relative phase. It does not solve a gap equation or model a macroscopic superconductor.

Inspect one normalized pair-sector analogyA normalized two-level pure state, not an interacting field simulation. Playback adds one radian per second to the relative phase; basis probabilities stay fixed. Current readings: Probability |0⟩: 71.1%; Probability |1⟩: 28.9%; Bloch (x, y, z): 0.78, 0.45, 0.42. All parameters are adjustable with the labeled controls below.xyz|0⟩|1⟩Basis probabilitiesP(0)71.1%P(1)28.9%
Bloch vector / P(0)P(1)Phase latitude
Probability |0⟩
71.1%
Probability |1⟩
28.9%
Bloch (x, y, z)
0.78, 0.45, 0.42
t = 0 s

A normalized two-level pure state, not an interacting field simulation. Playback adds one radian per second to the relative phase; basis probabilities stay fixed. Parameter changes pause playback and recompute the model at the current elapsed time. Reset restores both parameters and returns time to zero. Playback starts paused. Adjust either parameter, then choose Play or Step.

Look forA normalized two-amplitude factor is inspectable. Collective pairing, temperature, stiffness, and electromagnetic screening require the many-body calculation beyond this lab.

Check your understanding

At ξ = 0 with a nonzero uniform s-wave mean-field gap, what is the quasiparticle energy?

Try it yourself

Reverse the sign of ξ in the worked example while keeping Δ fixed. Find E and |v|², and explain the physical difference.

Take a moment to make a prediction or work it out on paper. Open a hint when you need one.

Give me a hint

The spectrum contains ξ², but the coherence factor contains ξ itself.

Compare with the solution

For ξ = −3 meV, E remains √13 meV ≈ 3.6056 meV. The occupation weight becomes (1+3/√13)/2 ≈ 0.9160. Modes below and above the chemical potential can have the same excitation energy while differing in their particle-hole character and ground-state occupation.

Take it with you

  • BCS pairing reorganizes many states near a Fermi surface.
  • The gap and coherence factors arise from a self-consistent paired mean field.
  • Phase stiffness and electromagnetic response add information beyond a pairing gap.

Read further

Original sources and deeper explanations to follow at your own pace.

Optional progress, saved in this browser when available. Revisit any lesson at any time.

Lesson not marked complete.