Delta potentials and derivative discontinuities
Derive a contact-interaction matching condition and its unique attractive bound state without treating a distribution as an ordinary function.
On this page
The question for today
What you’ll understand
- Derive the signed derivative jump of an attractive contact interaction.
- Normalize its bound state and track the units of interaction strength.
- Distinguish the operator domain from a free-particle differential expression.
A delta potential compresses an interaction into a point while retaining a finite integrated strength. It is useful because its effect can be stated exactly as an interface condition. The wavefunction stays continuous, but its slope changes abruptly. This model teaches why the same free Schrödinger equation away from a special point can belong to a different Hamiltonian once its domain is specified.
Integrate the equation before taking a limit
Write with . Since a delta distribution has inverse-length units, has units of energy times length. Integrate the stationary Schrödinger equation over a symmetric interval around zero. The integral of the bounded energy term tends to zero as the interval shrinks, while the contact term gives . The kinetic second derivative contributes the difference between the two one-sided slopes, fixing a finite jump with a definite sign.
The wavefunction itself remains continuous in this delta model. Allowing an arbitrary value jump would generate a derivative of a delta distribution in its second derivative, which the chosen interaction does not contain. This statement is a property of this particular point interaction, not every conceivable singular Hamiltonian. One may define other contact models by other boundary conditions, but they must be specified explicitly instead of being silently inserted into the delta-potential calculation.
Normalizability and matching leave one state
For , normalizability requires a decaying exponential on either side. Continuity makes the two amplitudes equal, giving with . Its right slope is and left slope is . Inserting their difference into the jump condition determines one positive decay constant, hence one bound energy. The attractive delta therefore has exactly one bound state for every positive strength, without a minimum attraction threshold.
An odd bound state cannot be hidden in this solution. Odd continuity would make its value at the origin zero, so the delta would have no effect there. A decaying free solution on either half-line whose endpoint value vanishes must then have zero amplitude. A repulsive delta reverses the jump sign and would require a negative decay constant for this ansatz, contradicting normalizability. It has scattering states but no negative-energy bound state on the full line.
A cusp carries physical information
The cusp does not mean probability leaks at the interaction point. For this real stationary bound state the probability current is zero on both sides, and the real matching strength is compatible with unitary evolution. A naive calculation using only the free differential expression would miss the contact energy at the cusp. One must apply the distributional equation with its matching domain, or use the corresponding quadratic energy form that includes the term .
A narrow square well approaches this contact model when its width tends to zero while its integrated attraction stays fixed. Holding depth fixed instead makes its integrated attraction vanish, a different limit. The contact model suppresses information about finite interaction range. It can describe long-wavelength phenomena relative to that range, but it is not evidence that microscopic forces truly have infinite height or that all short-range interactions share the same spectrum at arbitrary energies.
Work it through
Strength, decay, and probability
Use the kinetic coefficient and attractive strength . Find the bound decay constant, energy, normalization coefficient, and probability outside .
Rewrite the jump equation as . For the even exponential its left side is , giving . This sign is consistent only with attraction.
The energy is . Normalization gives , so for the positive phase choice.
Integrating both exterior tails beyond distance d gives . At 1.0 nm it is . The amplitude falls on length 1 nm, whereas the probability density falls on length 0.5 nm.
The state has decay constant 1 nm⁻¹, energy −1 eV, and amplitude coefficient 1 nm⁻¹ᐟ². About 13.5% of its probability lies farther than 1 nm from the contact interaction.
The living notebook
Explore the model
Interactive lab · function
Distinguish a value from a derivative
Reset and set both controls to coefficient a = 1 and position x = −1; predict tangent slope −2. Reset and set both controls to a = 1 and x = 1; predict slope +2 despite equal function values. This smooth quadratic is a derivative-reading exercise, not the cusped bound state; it contains no delta interaction or derivative jump at zero.
- y at chosen x
- 0.608
- Tangent slope · 2ax
- 1.35
- Signed area · ax³/3
- 0.182
This lab uses only y = ax². Playback traces the curve within the fixed integration interval from 0 to x; it does not estimate numerical error or change the chosen point. Parameter changes pause playback and recompute the model at the current elapsed time. Reset restores both parameters and returns time to zero. Playback starts paused. Adjust either parameter, then choose Play or Step.
Look forMatching a value does not by itself match a slope; the delta jump must be calculated from its actual boundary condition.
Pause & reason
Check your understanding
Your turn
Try it yourself
Keep but reduce attractive strength to . Find binding energy and probability within 1 nm of the origin. Then explain what changes if this interaction is made repulsive with the same strength magnitude.
Take a moment to make a prediction or work it out on paper. Open a hint when you need one.
Give me a hint
Decay constant is linear in strength, energy is quadratic, and the desired probability is the complement of the exterior tails.
Compare with the solution
Now and . The probability inside is . Reversing the interaction to repulsive reverses the slope jump. The decaying ansatz would then require , so no square-integrable negative-energy state exists. This is not a positive-energy bound state appearing above zero: the repulsive problem instead retains its continuum scattering spectrum.
Keep the idea
Take it with you
- A delta strength has units of energy times length and produces a signed derivative jump.
- A single attractive full-line delta has exactly one normalizable bound state.
- The matching domain and contact term must accompany the free differential expression.
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