Bound states and spectral structure

Solve and compare quantum bound-state problems using matching conditions, symmetry, radial equations, and controlled limiting behavior.

10 published lessons1 module347 min of guided study
  1. 01
    Bound states and spectral structurecore · 10 lessons

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Bound states and spectral structure

Solve and compare quantum bound-state problems using matching conditions, symmetry, radial equations, and controlled limiting behavior.

  1. 01

    Matching a finite square well

    Determine bound energies by joining oscillatory interior solutions to normalizable exterior tails.

    33 min
  2. 02

    Delta potentials and derivative discontinuities

    Derive a contact-interaction matching condition and its unique attractive bound state without treating a distribution as an ordinary function.

    32 min
  3. 03

    Double-well splitting and localized states

    Separate stationary parity eigenstates from localized superpositions and derive tunnelling in an isolated two-state approximation.

    34 min
  4. 04

    The radial equation and centrifugal barriers

    Separate a central potential, choose the radial measure correctly, and identify origin conditions and angular-momentum barriers.

    35 min
  5. 05

    Hydrogenic energies and degeneracy

    Use the Coulomb spectrum with reduced mass and separate orbital multiplicity from spin and physical level splittings.

    34 min
  6. 06

    Hydrogen wavefunctions and orbital nodes

    Separate radial and angular zeros and distinguish probability per volume from probability per radial shell.

    34 min
  7. 07

    Harmonic-oscillator ladder algebra

    Obtain energies and matrix elements from positive norms and operator commutators rather than solving each eigenfunction separately.

    35 min
  8. 08

    Coherent states and minimum uncertainty

    Construct displaced oscillator ground states, follow their moving means, and distinguish coherent widths from general uncertainty saturation.

    35 min
  9. 09

    Self-adjoint domains in one dimension

    Use a half-line Hamiltonian to show how boundary conditions determine unitary evolution, reflection phases, and possible bound states.

    38 min
  10. 10

    Counting bound states and approaching threshold

    Use parity thresholds, nodal order, and admissible variational trials to count and diagnose weakly bound states.

    37 min
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