Controlled approximations in quantum dynamics

Choose and test perturbative, variational, semiclassical, and adiabatic approximations by identifying small parameters and diagnosing their failure.

10 published lessons1 module280 min of guided study
  1. 01
    Controlled approximations in quantum dynamicsadvanced · 10 lessons

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Controlled approximations in quantum dynamics

Choose and test perturbative, variational, semiclassical, and adiabatic approximations by identifying small parameters and diagnosing their failure.

  1. 01

    Small couplings must be compared with energy gaps

    Derive stationary corrections and diagnose when a seemingly small perturbation strongly mixes states.

    28 min
  2. 02

    Diagonalize inside a degenerate subspace first

    Construct the correct zeroth-order combinations and connect near degeneracy with avoided crossings.

    28 min
  3. 03

    Trial states give upper bounds with a precise scope

    Use the Rayleigh quotient, optimize a Gaussian, and distinguish an energy bound from an error certificate.

    28 min
  4. 04

    Connect semiclassical waves across a simple turning point

    Match a decaying forbidden-region solution to its allowed-region phase and diagnose the WKB breakdown scale.

    28 min
  5. 05

    Endpoint phases quantize a closed orbit

    Derive the half-integer shift for two soft turning points and separate it from hard-wall quantization.

    28 min
  6. 06

    Tunneling splits a doublet without creating a decay rate

    Compare forbidden-region actions, coherent doublet oscillation, and Euclidean instanton estimates.

    28 min
  7. 07

    A weak drive accumulates a complex transition amplitude

    Use the interaction picture and finite-time interference while keeping time ordering and perturbative limits explicit.

    28 min
  8. 08

    A transition rate emerges in a restricted continuum window

    Derive the golden rule from a finite-time peak and check density, normalization, and depletion assumptions.

    28 min
  9. 09

    Slow following requires a smooth path and an isolated eigenstate

    Distinguish an adiabatic theorem from a local rate diagnostic and track the state rather than fixed basis populations.

    28 min
  10. 10

    A crossing sweep separates diabatic survival from ground-state following

    Apply the Landau–Zener formula with explicit slope, coupling, endpoints, and final-state labels.

    28 min
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